Q: Who was the first African American woman to be appointed Secretary of State, and the first woman to be appointed National Security Advisor?
A: Condoleezza Rice, who served as the 66th United States Secretary of State. Rice was the first female African-American secretary of state, as well as the second African American secretary of state (after Colin Powell), and the second female secretary of state (after Madeleine Albright). Rice was President Bush’s National Security Advisor during his first term, making her the first woman to serve in that position.